Engineering
Chemistry
Preparation of Amines
Test of amines
Question

Write the following reactions:
(i) Williamson's synthesis 
(ii) Mendius reaction 
(iii) Friedel Craft's Alkylation
(iv) Haloform reaction 
(v) Gattermann reaction
(vi) Carbylamine reaction

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Solution
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(i) Williamson Synthesis:

(ii) Mendius Reaction:
reducing of isonitrite.
(iii) Friedel Craft's Alkylation:
Refer to image 01
This is alkylation of aromatic compound.
(iv) Haloform Reaction:
Refer to Image 02.
This is specifically Iodoform Reaction.
(v) Gattermann Reaction
Refer to Image 03.
Diazonium Chloride on reaction with Cu and HCl gives.
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