Engineering
Chemistry
Payload and Barometric Distribution of Pressure
Question

What is Avogadro's law? Explain Boyle's law and Charle's law with graph.

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Solution
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(a) Avogadro's law:

V ∝ n      (at constant T and P)

V = k4n

Vn = constant (k4)

Boyle's law:

Mathematically, Boyle's law is written as,

V1P      (at constant T and n)
V=k1P
or, PV = k[1]
Where, P = Pressure, V = Volume, k= proportionality constant.
Suppose a gas has volume Vat pressure P1. At constant temperature, if pressure extended to Pand volume becomes V2, then according to Boyle's law,

P1V1 = P2V2 = constant.

or,    P1P2=V2V1

(see the figure 1)

Charle's law:
According to this law, "At constant pressure, the volume of gas increases or decreases by 1273 on increasing or decreasing each degree of temperature".

Mathematically, Charles law can be written as:

Suppose, the volume of gas is Vat temperature 0ºC. If temperature is increased as tºC then volume becomes Vt, then according to Charles law,
Vt=Vo+Vo273t

or, Vt=Vo(1+t273)

We can calculate the volume of given mass of gas at different temperatures.

(Follow the below figure 2).

For example:
Volume at 1oC(V1)=Vo(1+1273)
Volume at 10oC(V10)=Vo(1+10273)

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