Engineering
Chemistry
Hydrometallurgy and Leaching
Question

The diagram shows the sketch of an electrolytic cell used in the extraction of aluminium.

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Linked Question 1

At which electrode (A or B) is the aluminium formed?

A (Cathode)

At both A and B

B (Anode)

Cannot be determined

Solution
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Aluminium ions receive electrons at the negative electrode(Cathode) and are reduced to aluminium atoms:

A3+ + 3e → Al (reduction – gain electrons)

The molten aluminium sinks to the bottom of the cell, where it is tapped off.

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Linked Question 2

What is the substance of which the electrodes A and B are made?

Zinc and copper

Copper and iron

None of the above

Carbon and graphite

Solution
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The diagram shows an aluminium oxide electrolysis cell. Both the negative electrode (cathode) and the positive electrode (anode) are made of graphite, which is a form of carbon.

Hence, option A is correct.

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Linked Question 3

What are the two aluminium compounds present in the electrolyte C?

Pure alumina (Al2O3) and cryolite (Na3AlF6)

Cryolite, duralumin

Duralumin, magnalium

none of the above

Solution
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The two aluminium compounds present in the electrolyte C are:

1. Pure Alumina (aluminium oxide) Al₂O₃ and 

2. Cryolite (sodium aluminium fluoride) Na₃AlF.

Hence, option A is correct.

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