NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature dependent magnetic behavior (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are respectively

Engineering

Chemistry

Crystal Field Theory and Valence Bond Theory

Question

NiCl₂{P(C₂H₅)₂(C₆H₅)}₂ exhibits temperature dependent magnetic behavior (paramagnetic/diamagnetic). The coordination geometries of Ni²⁺ in the paramagnetic and diamagnetic states are respectively

tetrahedral and tetrahedral

square planar and tetrahedral

square planar and square planar

tetrahedral and square planar

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Ni⁺² → d⁸ configuration

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