Engineering
Chemistry
Isomerism in Coordination Compounds
Question

Indicate the types of isomerism exhibited by the following complex and draw the structures of the isomers: K[Cr(H2O)2(C2O4)2]

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Solution
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Both geometrical (cis-trans) and optical isomers for cis-form can exist.

a. Geometrical iscmers of K[Cr(H2O)2(C2O4)2]:

b. Optical lsomers {α and h} of Cls – K[Cr(H2O)2(C2O)4]:

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