Engineering
Chemistry
Compounds of Halogen Family
Question

Hydrolysis is the reaction of water with different substance. Several mechanisms are suggested like SN1, SN2..... etc.

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Linked Question 1

The product of hydrolysis for NCl3 is

NH3 and HOCl

HNO2 and HCl

N(OH)3 and HCl

NH3 and HCl

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Linked Question 2

For which of the pair of compounds the hydrolysis products are identical.

SOCl2 and HSO2Cl

None of these

PCl3 and AsCl3

BiCl3 and SbCl3    

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Linked Question 3

In which of the following cases the oxidation state of central atom gets changed on hydrolysis.

XeF4

XeF6

POCl3

HSO3Cl

Solution
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(i) XeF6(+6) + 3H+OH¯ XeO3(+6)+6HF

(iii)  3XeF4+4 +  6H+ OH¯  2Xe(O)  +  XeO3(+6)+12HF+32O2

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