Engineering
Chemistry
VSEPR Theory
Question

Hydrogen bonding originates from the dipole-dipole interaction between H-atom and any of the other atom like F, O, N and in somecases  with Cl atom. There are two types of H-bonding like intermolecular and intramolecular H– bonding.

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Linked Question 1

Which of the following molecule does not consist of intramolecular H–bonding.

chloral hydrate

ortho hydroxy benzaldehyde

ortho chlorophenol

chloral

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Linked Question 2

Which of the following plot for ρ (density) v/s T (temperature) for liquid H2O is correct:

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Ice has less density than water at all temperature but below boiling point.

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Linked Question 3

Which of following statement is incorrect.

o-nitrophenol can be separated from its meta and para isomer using its steam volatile property.

Boiling point of H2O2 is greater than that of H2O

Ethylene glycol is less viscous than glycerol.

In ice each 'O' atom is tetrahedrally arranged by four H-atoms which are all equidistant.

Solution
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In H2O2, extent of H-bonding is greater than that of water.
Glycerol is highly viscous than ethylene glycol because in glycerol per molecule number of –OH groups are three while in ethylene glycol they are two which can form intermolecular H-bond.
 
     Four H-atom are not equidistant    
    x2 > x1

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