Consider the reaction sequence from P to Q shown below. The overall yield of the major product Q from P is 75%. What is the amount in grams of Q obtained from 9.3 mL of P? (Use density of P=1.00 gmL–1, Molar mass of C = 12.0, H = 1.0, O = 16.0 and N = 14.0 g mol–1)
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Molecular weight of
aniline = M.wt. of C6NH7
= 72 + 7 + 14 = 93
density of P = 1 g mL–1
9.3 mL of P = 9.3 g P
= 1 : 1 : 1
so the mole of Q formed will be 0.1 mole and extent of reaction is 100% but if it is 75% yield.
Then amount of Q
The molecular formula of Q = C16H12ON2
so M.wt. of Q = 16 × 12 + 12 × 1 + 16 + 2 × 14
= 192 + 12 + 16 + 28
= 248 g
so amount of Q = 248 × 0.075
= 18.6 g
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