Engineering
Chemistry
Diazonium salt
Question

Consider the reaction sequence from P to Q shown below. The overall yield of the major product Q from P is 75%. What is the amount in grams of Q obtained from 9.3 mL of P? (Use density of P=1.00 gmL–1, Molar mass of C = 12.0, H = 1.0, O = 16.0 and N = 14.0 g mol–1)

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Solution
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Molecular weight of

aniline = M.wt. of C6NH7

           = 72 + 7 + 14 = 93

density of P = 1 g mL–1

9.3 mL of P = 9.3 g P

                   =9.39.3=0.1  mol  P

                                    = 1 : 1 : 1

so the mole of Q formed will be 0.1 mole and extent of reaction is 100% but if it is 75% yield.

Then amount of Q =0.1×75100=0.075  mol

The molecular formula of Q = C16H12ON2

so M.wt. of Q = 16 × 12 + 12 × 1 + 16 + 2 × 14

                      = 192 + 12 + 16 + 28

                      = 248 g

so amount of Q = 248 × 0.075

                         = 18.6 g

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