Engineering
Chemistry
Isomerism in Coordination Compounds
Question

Consider the complex ions, trans–[Co(en)2Cl2]+ (A) and cis –[Co(en)2Cl2]+ (B). The correct statement regarding them is :

Both (A) and (B) cannot be optically active.

both (A) and (B) can be optically active.

(A) cannot be optically active.

can be optically active, but (B) cannot be optically active.

JEE Advance
College PredictorLive

Know your College Admission Chances Based on your Rank/Percentile, Category and Home State.

Get your JEE Main Personalised Report with Top Predicted Colleges in JoSA

Solution

Trans-[Co(en)2Cl2]+


cis-[Co(en)2Cl2]+ → is optically active without plane of symmetry.