Engineering
Chemistry
Freundlich Adsorption
Question
Catalyst used in dimerisation of acetylene to prepare chloroprene is

HgSO4+H2SO4

Cu2CI2

Cu2CI2 + NH4CI

Cu2CI2 + NH4OH

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Solution
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Acetylene dimerized to give vinyl acetylene when it combines with hydrogen chloride to form 4-chloro-1, 2-butadiene, an allene derivative, which in presence of cuprous chloride (CU2CI2) and ammonium chloride (NH4CI), rearranges to form 2 – Chlorobuta – 1, 3 – diene.
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