Engineering
Chemistry
Molecular Orbital Theory or MOT
Question
Column - I Column - II
(A)  dx2-yatomic orbital (P) One nodal plane
(B) py atomic orbital (Q) Two nodal planes
(C)  σPx molecular orbital (R) ψ (g) [gerade]
(D)  π*Py molecular orbital (S) ψ (u) [Ungerade]
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Solution

 

              No. of nodal planes = 2
             dx2y2 has even no. of nodal planes hence it is gerade (i.e. ψg )

             No. of nodal plane =1
             py has  odd no of nodal planes hence it is ungerade (i.e. ψu )

           No. of nodal plane = 0
           M.O. has even no of nodal planes hence it is gerade (i.e.ψg )

         No. of nodal plane = 2
         π2py* has even no of nodal plane hence it is gerade (i.e. ψg )

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